Ce^³⁺/Eu^²⁺ Doped Al<inf>2</inf>O<inf>3</inf> Coatings Formed by Plasma Electrolytic Oxidation of Aluminum: Photoluminescence Enhancement by Ce^³⁺→Eu^²⁺ Energy Transfer

Abstract

Plasma electrolytic oxidation (PEO) of aluminum in electrolytes containing CeO2 and Eu2O3 powders in various concentrations was used for creating Al2O3 coatings doped with Ce3+ and Eu2+ ions. Phase and chemical composition, surface morphology, photoluminescence (PL) properties and energy transfer from Ce3+ to Eu2+ were investigated. When excited by middle ultraviolet radiation, Al2O3:Ce3+/Eu2+ coatings exhibited intense and broad emission PL bands in the ultraviolet/visible spectral range, attributed to the characteristic electric dipole 4f05d1→4f1 transition of Ce3+ (centered at about 345 nm) and 4f65d1→4f7 transition of Eu2+ (centered at about 405 and 500 nm). Due to the overlap between the PL emission of Al2O3:Ce3+ and the PL excitation of Al 2+2O3:Eu , energy transfer from Ce3+ sensitizer to the Eu2+ activator occurs. The energy transfer is identified as an electric dipole-dipole interaction. The critical distance between Eu2+ and Ce3+ ions in Al2O3 was estimated to be 8.6 Å by the spectral overlap method.