Please use this identifier to cite or link to this item: https://physrep.ff.bg.ac.rs/handle/123456789/663
Title: Symmetry-Based Electron–Phonon Decoupling and Jahn–Teller Theorem Violation in Specific Crystalline Structures
Authors: Milošević, Ivanka 
Nikolić, Božidar 
Damnjanović, Milan 
Keywords: electron–phonon interaction;group theory;Jahn–Teller theorem;symmetry
Issue Date: 1-Dec-2019
Journal: Physica Status Solidi (B) Basic Research
Abstract: 
There is a special class of crystalline structures which, in the first-order perturbation theory, allow for the electronic system to be decoupled from the phonon degrees of freedom. Such systems and electronic states are identified on the basis of symmetry and group theory. To arise such electron–phonon decoupling, three general symmetry-based conditions are to be satisfied. By giving clear formulation of these criteria, a recipe for engineering the configurations with electron–phonon coupling deficiency is presented. The Jahn–Teller theorem validity is also discussed and it is shown that breakdown of the theorem in any dimension is possible, that is, there are specific configurations of molecules, polymers, layers, and 3D crystals, whose total energy is optimized by hosting a ground electronic state that is orbitally degenerate.
URI: https://physrep.ff.bg.ac.rs/handle/123456789/663
ISSN: 0370-1972
DOI: 10.1002/pssb.201900242
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