Effect of chemical modifications and coating with Cu-based nanoparticles on the electro-physical properties of jute fabrics in a condition of high humidity

Abstract

The electro-physical properties of raw, alkali and oxidatively modified jute fabrics were investigated as complex phenomena of the interactions between the fabrics’ chemical composition, carboxyl group content, crystallinity, structural characteristics, moisture sorption, and frequency of the electric field. At 80% relative air humidity, chemically modified jute fabrics have 38–179% and 1.7–5.4 times higher dielectric loss tangent and effective relative dielectric permeability compared to unmodified. To further improve these properties, fabrics were treated with CuSO4 and Cu-based nanoparticles were in situ synthesized on their surfaces by reduction. A few smaller agglomerates of Cu-based nanoparticles were observed across the alkali modified fabric's surface, while smaller irregularly shaped and larger agglomerates were distributed over the oxidatively modified fabric's surface. Regardless of the type of synthesized nanostructures (metallic Cu, copper oxide (Cu2O or CuO) or their mixtures), excellent fabrics’ effective relative dielectric permeability is guaranteed. Precisely, exploitation in specific conditions that contribute to copper reduction will make jute fabrics able to store 21–163 times more energy from an external electric field than before the exploitation, which will extend their lifetime. On the other hand, with increasing the total content of Cu after the reduction and formation of agglomerates of Cu-based nanoparticles, the movements of cellulose, hemicelluloses, and lignin molecules become difficult resulting in lower energy dissipation within the chemically modified than within unmodified fabric. Applied chemical modification and coating with Cu-based nanoparticles enables designing fabrics with predictable electro-physical properties, which is very important from the application point of view.