Resonant vibrational excitation and de-excitation of N<inf>2</inf>(v) by low-energy electrons

Abstract

We have calculated cross sections and rate coefficients for low-energy electron impact excitation of the nitrogen molecule from vibrationally excited levels N2(v) 1-8. Calculations are performed in the 2∏g shape resonance energy region, from 0 to 5 eV. The cross sections are determined by using our recent integral cross section measurements of the ground level vibrational excitation and the most recent cross sections for elastic electron scattering, applying the principle of detailed balance. The rate coefficient calculations are performed for the Maxwellian electron energy distribution. By using extended Monte Carlo simulations, the electron energy distribution functions (EEDF) and the rate coefficients are also determined for the nonequilibrium conditions, in the presence of the homogeneous external electric field for the typical, moderate values of the electric field over gas number density ratios, E/N. © 2008 American Chemical Society.